. alpha.-Regioselectivity in palladium-catalyzed arylation of acyclic enol ethers

…, I Candiani, A Bedeschi, S Penco…

Index: Cabri, Walter; Candiani, Ilaria; Bedeschi, Angelo; Penco, Sergio; Santi, Roberto Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1481 - 1486

Full Text: HTML

Citation Number: 191

Abstract

The direct functionalization of olefins with aryl and heterocyclic derivatives (Heck reaction) k one of the more interesting and important palladium-catalyzed reactions because of the compatibility of several functionalities, the mild conditions, and the simplicity of the procedure.'However, the low degree of regioselectivity observed with some classes of olefins is the major drawback. During the last decade this limitation has been ...