Reactivity of 1-(9-fluorenyl) germatrane and the crystal structure of 9-trimethylgermylfluorene

…, LG Kuz'mina, PL Shutov, SS Karlov, AA Selina…

Index: Churakov; Kuz'mina; Shutov; Karlov; Selina; Zaitseva Russian Journal of Inorganic Chemistry, 2002 , vol. 47, # 7 p. 983 - 986

Full Text: HTML

Citation Number: 1

Abstract

Résumé/Abstract The reactivity of 1-(9-fluorenyl) germatrane (I) containing several reaction centers (the Ge-C apical bond, Ge-O equatorial bonds, mobile hydrogen atom in the 9- position of the fluorenyl group, and aromatic rings) is studied. Its interaction with reagents that could involve each of the centers is investigated. The reactivities of I and 9- trimethylgermylfluorene (II), a fluorenyl derivative of tetracoordinated germanium, are ...