The Journal of Organic Chemistry

Synthesis and coordinating properties of heterocyclic-substituted tertiary phosphines

SS Moore, GM Whitesides

Index: Moore, Stephen S.; Whitesides, George M. Journal of Organic Chemistry, 1982 , vol. 47, # 8 p. 1489 - 1493

Full Text: HTML

Citation Number: 51

Abstract

Method A involved reaction between a heteroaryl organolithium reagent and phosphorous trichloride; method B involved the reaction between a 2-(trimethylsily1)-substituted heteroaromatic and a phosphorous (111) halide.* From ref 9. The requisite organolithium reagent was prepared by metal-halogen exchange between 2-bromothiazole and n-BuLi. 2- Lithiothiazole was prepared by metalation of thiazole with n-BuLi.