Preparative synthesis of vinyl diamondoids

…, BA Tkachenko, NA Fokina, PR Schreiner

Index: Fokin, Andrey A.; Butova, Ekaterina D.; Barabash, Anastasiya V.; Huu, Nhan N.; Tkachenko, Boryslav A.; Fokina, Natalie A.; Schreiner, Peter R. Synthetic Communications, 2013 , vol. 43, # 13 p. 1772 - 1777

Full Text: HTML

Citation Number: 3

Abstract

We describe a convenient four-step preparation of 1- vinyl adamantane, 1- vinyl diamantane, and 4,9-divinyl diamantane from the respective diamondoid acetic acids in 50–80% isolated yields involving esterification, reduction, and hydrobromination/dehydrobromination. ... Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free ...