New aspect of nucleophilic reactivity of tertiary phosphine oxides. R3PO-POCl3 binary system

MV Kazantseva, BV Timokhin, AV Rokhin…

Index: Kazantseva; Timokhin; Rokhin; Blazhev; Golubin; Rybakova Russian Journal of General Chemistry, 2001 , vol. 71, # 8 p. 1233 - 1235

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Citation Number: 6

Abstract

Abstract The reaction of tertiary phosphine oxides with phosphorus oxychloride was found to give triorganylphosphonium dichlorophosphates R 3 PCl+ PO 2 Cl 2-rather than phosphorylphosphonium salts R 3 P· OPOCl 2. Mixtures of the reagents, called binary ...