Structural Chemistry

A comparison of X-ray crystal structures including methyl 3, 5-bis (hydroxymethyl) benzoate, its phenylethynyl extended derivative in polymorphous forms and the …

F Katzsch, D Eißmann, E Weber

Index: Katzsch, Felix; Eissmann, Diana; Weber, Edwin Structural Chemistry, 2012 , vol. 23, # 1 p. 245 - 255

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Citation Number: 6

Abstract

Abstract Considering the specific supramolecular synthon design of carboxylic acid and alcoholic hydroxyl groups in the field of crystal engineering, we compared the solid state structures of particular benzoates and corresponding acids 1–4 both in the non-spacered (1, 2) and spacered (3, 4) forms. Based on the single crystal X-ray study, there is only a slight influence of the phenylacetylene spacer with regard to the layer lattice arrangement of the ...