Reactions of fluoroölefins with sulfur trioxide

DC England, MA Dietrich…

Index: England,D.C. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 6181 - 6188

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Citation Number: 82

Abstract

Sulfonic-carboxylic x1 X? R Sultone halide FFF 1 11 c1 c1 F 111 IV F c1 c1 v\-IFF c1 TI1 IX c1 FF VI11 X opening at the 8-0 bond is indicated by the presence of a carbonyl group in the final product. In the second step, halogen ion, XI@, is expelled. It is of interest that in those cases in which a choice between C1-and F-exists, the expelled anion is always C1- (compounds I11 and VIII). In the final step, the expelled anion displaces triethylamine from ...