Tetrahedron

8-Methylquinoline palladacycles: stable and efficient catalysts for carbon–carbon bond formation

…, P Hogg, R Grigg, M Nurnabi, J Hinsley, V Sridharan…

Index: Evans, Paul; Hogg, Paul; Grigg, Ronald; Nurnabi, Mohamed; Hinsley, Joanne; Sridharan, Visuvanathar; Suganthan, Selvaratnam; Korn, Stewart; Collard, Simon; Muir, Jane E. Tetrahedron, 2005 , vol. 61, # 41 p. 9696 - 9704

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Citation Number: 40

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Cyclopalladated, phosphine free, 8-methyl quinoline based complexes (2a–j) are excellent catalysts for the Heck vinylation of aryl iodides and bromides with turnover numbers of greater than 25 million observed in some cases. The catalysts are air and moisture stable.