Preparation of a Yb (III)??Incorporated porous polymer by post??Coordination: Enhancement of gas adsorption and catalytic activity

…, MC Cha, HW Park, JY Chang

Index: Kim, Hyungwoo; Cha, Min Chul; Park, Hyun Woo; Chang, Ji Young Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 24 p. 5291 - 5297

Full Text: HTML

Citation Number: 7

Abstract

ABSTRACT We synthesized a Yb (III)-incorporated microporous polymer (Yb-ADA) and studied its gas adsorption property and catalytic activity. The adamantane-based porous polymer (ADA) was obtained from an ethynyl-functionalized adamantane derivative and 2, 5- dibromoterephthalic acid through Sonogashira–Hagihara cross-coupling. ADA had two carboxyl groups which were used for Yb (III) coordination under basic conditions. The ...