Syntheses and crystal structures of ferrocenyl derivatives of biphenyl

DA Lemenovskii, MV Makarov, VP Dyadchenko…

Index: Lemenovskii; Makarov; Dyadchenko; Bruce; Larkin; Averkiev; Starikova; Antipin Russian Chemical Bulletin, 2003 , vol. 52, # 3 p. 607 - 615

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Citation Number: 8

Abstract

Abstract Arylation of ferrocene with substituted biphenyldiazonium tetrafluoroborates afforded 4-bromo-, 4-nitro-, and 4-cyano-4"-ferrocenylbiphenyls. 4-Nitro-and 4-cyano-4"- ferrocenylbiphenyls were studied by X-ray diffraction analysis. In the crystals of 4-nitro-4"- ferrocenylbiphenyl, the molecules are linked via stacking π-π interactions.