Journal of the American Chemical Society

Reactions of Hydrogen Peroxide. V. 1 Alkaline Epoxidation of Acrolein and Methacrolein

GB Payne

Index: Payne Journal of the American Chemical Society, 1959 , vol. 81, p. 4901,4904

Full Text: HTML

Citation Number: 70

Abstract

An early attempt to epoxidize simple@ unsaturated aldehydes by means of hydrogen peroxide under alkaline conditions was reported by Weitz and Scheffer2 in their original study of the epoxidation of a, P-unsaturated ketones. They used a relatively large amount of caustic (as high as 40 mole% based on hydrogen peroxide) in attempts to epoxidize both cinnamaldehyde and crotonaldehyde, but observed only acidic products from both ...

Mechanisms of formation of adducts from reactions of glycida...

[Golding, Bernard T.; Slaich, Pritpal K.; Kennedy, Gordon; Bleasdale, Christine; Watson, William P. Chemical Research in Toxicology, 1996 , vol. 9, # 1 p. 147 - 157]

Juliá–Colonna stereoselective epoxidation of some α, β-unsat...

[Ray, Peter C.; Roberts, Stanley M. Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 2 p. 149 - 153]

… of the enantioselective properties of the quinohemoprotein...

[Machado, Sonia Salgueiro; Wandel, Ute; Jongejan, Jaap A.; Straathof, Adrie J. J.; Duine, Johannis A. Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 1 p. 10 - 20]