Dalton Transactions

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine

D Breyer, T Braun, A Penner

Index: Breyer, David; Braun, Thomas; Penner, Anna Dalton Transactions, 2010 , vol. 39, # 32 p. 7513 - 7520

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Citation Number: 37

Abstract

The hydrido complexes trans-[Pd (H)(4-C5NF4)(PiPr3) 2](3) and trans-[Pd (H)(4- C5NF4)(PCy3) 2](5) can be prepared by reaction of trans-[Pd (F)(4-C5NF4)(PiPr3) 2](2) or trans-[Pd (F)(4-C5NF4)(PCy3) 2](4) with HBpin (HBpin= 4, 4, 5, 5-tetramethyl-1, 3, 2- dioxaborolane, pinacolborane). The iodo and triflato complexes trans-[Pd (I)(4- C5NF4)(PiPr3) 2](7) and trans-[Pd (OTf)(4-C5NF4)(PiPr3) 2](9) are generated on ...