e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Photochemical reactivity of keto imino ethers. VI. Type I rearrangement and (2+ 2) photocycloaddition to the carbon-nitrogen double bond of 2-oxazolin-4-ones
RM Rodehorst, TH Koch
Index: Rodehorst,R.M.; Koch,T.H. Journal of the American Chemical Society, 1975 , vol. 97, p. 7298 - 7304
Abstract: The Norrish type I cleavage and (2+ 2) photocycloaddition reactions of five oxazolinones, 2-phenyl-(7a), 2-ethoxy-(7b), 2-p-methoxyphenyl-(7~). 2-m-methoxyphenyl- (la), and 2-(rn-trifluoromethylphenyl)-2-oxazolin-4-one(le), are described. The Norrish type I cleavage yields oxiryl isocyanates loa, lob, and lOe, and the (2+ 2) photocycloaddition of the oxazolinones to 1, l-dimethoxyethene and furan yields the azabicyclic products lla, llc, lld, ...
