Unimolecular H 2 elimination during the liquid phase radiolysis and photolysis of alkane-alkane mixtures

L Wojnárovits, G Földiák

Index: Wojnarovits, L.; Foeldiak, G. Acta Chimica Academiae Scientiarum Hungaricae, 1980 , vol. <1> 105, p. 27 - 38

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Citation Number: 10

Abstract

Unimolecular H 2 elimination from alkanes was investigated in cyclopentane-cyclohexane, n- hexane-cyclohexane and cyclohexane-cyclooctane mixtures during fluradiolysis and 7.6 eV photolysis. During the radiolysis of all systems, and when the fluorescence shift law allowed it, during the photolysis as well, inhibited H 2 detachment was observed from the first component and sensitized hydrogen molecule elimination from the second. It has been ...