Journal of the American Chemical Society

Some Reactions of Dialkylacetylenes1

EA Bried, GF Hennion

Index: Bried; Hennion Journal of the American Chemical Society, 1938 , vol. 60, p. 1718

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Citation Number: 10

Abstract

A previous communication2 in this series reported a rapid preparation of dialkylacetylenes involving the simultaneous interaction of sodium acetylide, sodamide and alkyl halides in liquid ammonia. This work has been extended with three objectives in mind:(1) to study the behavior of higher alkyl halides in the dialkylacetylene synthesis;(2) to study reactions of dialkylacetylenes; and (3) to prepare dialkylacetylene derivatives suitable for rapid ...