Inorganic chemistry

Halide, amide, cationic, manganese carbonylate, and oxide derivatives of triamidosilylamine uranium complexes

BM Gardner, W Lewis, AJ Blake, ST Liddle

Index: Gardner, Benedict M.; Lewis, William; Blake, Alexander J.; Liddle, Stephen T. Inorganic Chemistry, 2011 , vol. 50, # 19 p. 9631 - 9641

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Citation Number: 25

Abstract

We recently embarked on a program of research to investigate the structure, bonding, and reactivity of complexes that contain uranium–metal bonds;(27-34) this was stimulated by their paucity in the literature compared to the well-developed area of metal–metal bonding in the d-block.(6, 7) We have found the Tren TMS ligand to be an excellent ancillary ligand for complexes containing uranium–metal bonds, as demonstrated by our use of the complexes [U(Tren TMS ...