Journal of the American Chemical Society

THE EFFECT OF STRUCTURE OF ORGANIC HALIDES ON THEIR RATE OF REACTION WITH INORGANIC HALIDES. II. THE EFFECT OF THE METHYLTHIO …

WR Kirner

Index: Kirner Journal of the American Chemical Society, 1928 , vol. 50, p. 2452

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Citation Number: 26

Abstract

A study of the effect of a sulfur atom on the reactivity of an o-chlorine atom which is in the same molecule and separated by one, two or three methylene groups should be of interest in connection with the “acid theory” for the mechanism of skin vesication of mustard gas proposed by Lynch, Smith and Marshall2 and contradicted by later work of Peters and Walker. 3 To make the conditions for this investigation as simple as possible it was ...

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