Reductive cleavage of the carbon??phosphorus bond with alkali metals. I. Cleavage of functionalised triphenylphosphines; formation of secondary and primary …

PHM Budzelaar, JA van Doorn…

Index: Recueil des Travaux Chimiques des Pays-Bas, , vol. 110, # 10 p. 420 - 432

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Citation Number: 37

Abstract

... In the second step, the electron is transferred at the orbital Page 2. Recueil des Travaux Chimiques des Pays-Bas, 1 lOjlO, October 1991 42 1 Na Ph,P + 2e- Ph,P- + RBr Ph,P- + Br(CH,),Br Ph2P- + 2-C1C6H4C00 1-22 23-28 ...