Regioselective aliphatic carbon–carbon bond cleavage by a model system of relevance to iron-containing acireductone dioxygenase

CJ Allpress, K Grubel, E Szajna-Fuller…

Index: Allpress, Caleb J.; Grubel, Katarzyna; Szajna-Fuller, Ewa; Arif, Atta M.; Berreau, Lisa M. Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 659 - 668

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Citation Number: 25

Abstract

Mononuclear Fe (II) complexes ([(6-Ph2TPA) Fe (PhC (O) C (R) C (O) Ph)] X (3-X: R= OH, X= ClO4 or OTf; 4: R= H, X= ClO4)) supported by the 6-Ph2TPA chelate ligand (6-Ph2TPA= N, N-bis ((6-phenyl-2-pyridyl) methyl)-N-(2-pyridylmethyl) amine) and containing a β-diketonate ligand bound via a six-membered chelate ring have been synthesized. The complexes have all been characterized by 1H NMR, UV–vis, and infrared spectroscopy and variably by ...