Russian journal of organic chemistry

Tertiary Acetylenic Alcohols and Diols on the Basis of Phenylacetylene and 2-Methyl-3-butyn-2-ol

VI Potkin, EA Dikusar, NG Kozlov

Index: Potkin; Dikusar; Kozlov Russian Journal of Organic Chemistry, 2002 , vol. 38, # 9 p. 1260 - 1265

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Citation Number: 3

Abstract

Abstract A procedure has been proposed for the synthesis of tertiary acetylenic alcohols and diols by treatment of phenylacetylene or 2-methyl-3-butyn-2-ol with butyllithium and subsequent reaction of lithium phenylacetylide or lithium 4-lithio-2-methyl-3-butyn-2-olate thus obtained with alicyclic, aromatic, and terpene ketones.