Rhodium (III)-catalyzed N-nitroso-directed C–H olefination of arenes. High-yield, versatile coupling under mild conditions

B Liu, Y Fan, Y Gao, C Sun, C Xu…

Index: Kano, Shinzo; Tanaka, Yasuyuki; Sugino, Eiichi; Shibuya, Shiroshi; Hibino, Satoshi Synthesis, 1980 , # 9 p. 741 - 742

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Citation Number: 106

Abstract

... higher (>90%), but still, dn-3a was predominantly formed in low yield under most of the evaluated conditions (entries 5–9, Table S1 ... scope of the olefin coupling partner by reacting with 1a (Table 3). A variety of monosubstituted olefins, ethyl acrylate (2p), styrene (2q), p-F-styrene ...