Liquid crystalline dimers 1 (dimesogens) consisting of two identical (symmetrical) or non-identical (non-symmetrical) mesogenic units have gained attention as these are regarded as model compounds for main chain 2 and side chain liquid crystalline polymers. 3 The non-symmetrical dimers are markedly different from those of symmetrical ones as they exhibit interesting polymorphic sequence 4 and stabilize wide range chiral nematic (N*) 5a and smectic A (SmA) mesophases. 5b ...