Tetrahedron

Synthesis and optical/thermal properties of low molecular mass V-shaped materials based on 2, 3-dicyanopyrazine

…, E Westphal, IH Bechtold, AJ Bortoluzzi, H Gallardo

Index: Cristiano, Rodrigo; Westphal, Eduard; Bechtold, Ivan H.; Bortoluzzi, Adailton J.; Gallardo, Hugo Tetrahedron, 2007 , vol. 63, # 13 p. 2851 - 2858

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Citation Number: 57

Abstract

A novel series of luminescent low molecular mass materials containing a 2, 3- dicyanopyrazine central core were synthesized through an esterification reaction between diphenol 10 and different aromatic carboxylic acids 1–6, containing terminal long alkyl chains. They have a similar V-shaped geometry with lack of planarity between the two arms, confirmed by the X-ray structure of the central core. The optical and thermal properties of ...