Synthetic Communications

First Iodine-Catalyzed Deallylation of Reactive Allyl Methylene Esters

BR Nawghare, PD Lokhande

Index: Nawghare, Beena R.; Lokhande, Pradeep D. Synthetic Communications, 2013 , vol. 43, # 14 p. 1955 - 1963

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Abstract

C-Allyl cleavage has been developed using the inexpensive and mild reagent iodine in dimethylsulfoxide. A variety of compounds with active methylene groups were C-deallylated using this reagent. This method is efficient and operationally simple in comparison to the methods using transition-metal complexes. ... Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free ...

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