Palladium nanoparticles on thermoresponsive hydrogels and their application as recyclable Suzuki–Miyaura coupling reaction catalysts in water

MC Hong, MC Choi, YW Chang, Y Lee…

Index: Hong, Myeng Chan; Choi, Myung Chan; Chang, Young Wook; Lee, Yongwoo; Kim, Jongsik; Rhee, Hakjune Advanced Synthesis and Catalysis, 2012 , vol. 354, # 7 p. 1257 - 1263

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Citation Number: 24

Abstract

Abstract Palladium nanoparticles were immobilized on PNIPAM: 4-VP hydrogels. The resultant püalladium catalysts showed high activities for Suzuki–Miyaura coupling reactions in water. The recyclability of the catalysts was improved by using 4-VP as a co-monomer in the hydrogels due to reduced Pd leaching during the reactions.