Cobalt-catalyzed reaction of nitric oxide with aryl-substituted olefins in the presence of tetrahydroborate ion

…, K Kobayashi, S Oka, S Tanimoto

Index: Okamoto, Tadashi; Kobayashi, Kenji; Oka, Shinzaburo; Tanimoto, Shigeo Journal of Organic Chemistry, 1987 , vol. 52, # 23 p. 5089 - 5092

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Citation Number: 26

Abstract

A new transition-metal-catalyzed reaction of nitric oxide with aryl-substituted olefins in the presence of BH4-has been reported, where the oximes of alkyl aryl ketones are the products. The most successful results were obtained by using styrene and its ring- substituted derivatives as the substrate and Co (DH),(py) Cl as the catalyst. A process involving the intermediate formation of a metal-alkyl complex and its subsequent ...