Inorganica Chimica Acta

Single end to end azido bridged adduct of a tridentate schiff base copper (II) complex: Synthesis, structure, magnetism and catalytic studies

S Banerjee, C Adhikary, C Rizzoli, R Pal

Index: Banerjee, Sourajit; Adhikary, Chandan; Rizzoli, Corrado; Pal, Rammohan Inorganica Chimica Acta, 2014 , vol. 409, # PART B p. 202 - 207

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Citation Number: 10

Abstract

Abstract Copper (II) azido complex [CuL (μ-1, 3-N 3)] n (1) of a NNO donor tridentate Schiff base (HL= 2-[1-(methylamino-ethylimino)-methyl]-phenol containing single end-to-end μ-1, 3-azido bridged 1D infinite chain has been synthesized and characterized by elemental analysis, FT-IR spectroscopy. X-ray single crystal structure analysis reveals that in 1, the central copper (II) ion displays a distorted square pyramidal coordination geometry and ...