Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum (IV, VI) complexes: relevance to …

JP Caradonna, PR Reddy, RH Holm

Index: Caradonna, John P.; Reddy, P. Rabindra; Holm, R. H. Journal of the American Chemical Society, 1988 , vol. 110, # 7 p. 2139 - 2144

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Citation Number: 88

Abstract

Abstract: The kinetics and mechanism of the oxygen atom transfer reactions Mo02 (L- NS2)+(RF) 3P-MoO (L-NS2)(DMF)+(RF) 3P0 (1) and MoO (L-NS2)(DMF)+ XO-L Md2 (L- NS2)+ X, with X=(RF) 2S0 (2) and 3-fluoropyridine N-oxide (3), have been investigated in DMF solutions (L-NS2= 2, 6-bis (2, 2-diphenyl-2-mercaptoethyl) pyridine (2-), RF= pC, H4F).