Heteroatom Chemistry

Diastereoselective addition of Di??(trimethylsilyl) phosphite to chiral N??(R)?螃窿?methylbenzyl and N??(1??methoxycarbonyl??iso??pentyl) Schiff bases of various aldehydes

J Lewkowski, R Karpowicz

Index: Lewkowski, Jaroslaw; Karpowicz, Rafal Heteroatom Chemistry, 2010 , vol. 21, # 5 p. 326 - 331

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Citation Number: 16

Abstract

Abstract The addition of bis-(trimethylsilyl) phosphite to chiral imines of several aldehydes was diastereoselective. The separation of predominant diastereoisomers of a majority of formed aminophosphonic acids has been observed. Moreover, the ferrocene-derived acid 5d occurred in diastereoselectivity up to 100%.© 2010 Wiley Periodicals, Inc. Heteroatom Chem 21: 326–331, 2010; Published online in Wiley InterScience (www. interscience. ...