Journal of the Chemical Society (Resumed)

639. Reactions of fluorocarbon radicals. Part XI. Synthesis and some reactions of trifluoromethanethiol and trifluoromethanesulphenyl chloride

RN Haszeldine, JM Kidu

Index: Haszeldine; Kidd Journal of the Chemical Society, 1953 , p. 3219,3225

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Citation Number: 39

Abstract

CF,-S-SS* CF,+ CF,. SCF3+ CF,. S. SCF,+ CF,* S-CF,+ S The reaction of trifluoroiodomethane with sulphur is best carried out in an autoclave at 310, since the yield of bistrifluoromethyl disulpbide is then high (75y0), and the formation of carbon disulphide