Journal of organometallic chemistry

Synthesis of 1, 4-disilacyclohexa-2, 5-dienes

J Yang, I Guzei, JG Verkade

Index: Yang, Jinchao; Guzei, Ilia; Verkade, John G Journal of Organometalic Chemistry, 2002 , vol. 649, # 2 p. 276 - 288

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Citation Number: 9

Abstract

Title compounds of the type 2, 3, 5, 6-tetraphenyl-1, 4-di-X-1, 4-di-Y-1, 4-disilacyclohexa-2, 5- diene wherein X= Y= NMe2 (4); X= NMe2, Y= Cl (cis, trans-5); X= NMe2, Y= Me [(trans)-6] and X= t-Bu, Y= Cl (trans-8) were synthesized from Si2 (NMe2) 5Cl, sym-Si2 (NMe2) 4Cl2, sym-Si2 (NMe2) 4Me2, and sym-Si2Cl4 (t-Bu) 2, respectively, in the presence of diphenylacetylene at 200° C. Similarly the analogous title compound from the combination ...