Structure of C, N-chelated nButyltin (IV) fluorides and their use as fluorinating agents of some chlorosilanes, chlorophosphine and metal halides

…, P Novák, M Nádvorník, Z Padělková, I Císařová…

Index: Svec, Petr; Novak, Petr; Nadvornik, Milan; Padelkova, Zdenka; Cisarova, Ivana; Kolarova, Lenka; Ruzicka, Ales; Holecek, Jaroslav Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1390 - 1395

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Citation Number: 15

Abstract

The tin atom in the solid-state structure of {2-[(CH3) 2NCH2] C6H4} nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3) 2NCH2] C6H4} nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.