In pursuit of cyclopropanethione: cyclopropanethione S-oxide and S, S-dioxide

E Block, A Schwan, DA Dixon

Index: Block, Eric; Schwan, Adrian; Dixon, David A. Journal of the American Chemical Society, 1992 , vol. 114, # 9 p. 3492 - 3499

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Citation Number: 24

Abstract

Abstract: The geometries of cyclopropanethione (la), methylenethiuane (2a), cyclopropanethione S-oxide (lb), methylenethiirane S-oxide (Zb), cyclopropanethione S, S- dioxide (IC), methylenethiirane S, S-dioxide (2c), thioformaldehyde S $-dioxide (sulfene), and the tetramethyl derivatives of lb and 2b, tetramethylcyclopropanethione S-oxide (Id) and 3, 3-dimethyl-2-isopropylidenethiirane S-oxide (td), respectively, were optimized at the ...