Synthesis and photoinitiating properties of N-substituted 2, 6-diisopropylanilines

…, NV Shekleina, VV Shelkovnikov

Index: Kolchina; Shekleina; Shelkovnikov Russian Journal of Organic Chemistry, 2011 , vol. 47, # 6 p. 855 - 861

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Abstract

Abstract Reactions of 2, 6-diisopropylaniline and its 4-bromo and 4-thiocyanato derivatives with methyl iodide in dimethylformamide in the presence of potassium carbonate gave exclusively the corresponding N, N-dimethyl-substituted products. Heating of 2, 6- diisopropylaniline and 2, 6-diisopropyl-4-thiocyanatoaniline with methyl iodide without a solvent afforded only N-methyl derivatives.