A Series of Red??Light??Emitting Ionic Iridium Complexes: Structures, Excited State Properties, and Application in Electroluminescent Devices

…, Q Zhao, QL Fan, W Huang

Index: Liu, Shu-Juan; Zhao, Qiang; Fan, Qu-Li; Huang, Wei European Journal of Inorganic Chemistry, 2008 , # 13 p. 2177 - 2185

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Citation Number: 33

Abstract

Abstract A series of ionic diiminoiridium complexes [Ir (piq-C∧ N) 2 (LN∧ N)](PF 6) were prepared, where piq-C∧ N is 1-phenylisoquinolinato and LN∧ N are bidentate N- coordinating ligands: 2, 2′-bipyridine (bpy), 4, 4′-dimethyl-2, 2′-bipyridine (mbpym), 5, 5′-bis (thiopen-2-yl)-2, 2′-bipyridine (tbpyt), and 5, 5′-bis (9, 9-dioctylfluoren-2-yl)-2, 2′- bipyridine (FbpyF). X-ray diffraction studies of [Ir (piq) 2 (mbpym)](PF 6) revealed that the ...