Journal of the American Chemical Society

X-ray crystallographic, chemical, and spectroscopic studies of the palladium dichloride complexes of cyclonona-1, 5-diene, cycloocta-1, 5-diene, cycloocta-1, 4-diene, …

MF Rettig, RM Wing

Index: Rettig,M.F.; Wing,R.M.; Wiger,G.R. Journal of the American Chemical Society, 1981 , vol. 103, p. 2980

Full Text: HTML

Citation Number: 31

Abstract

Abstract: The crystal structures of three of the title complexes are reported and discussed; the fourth complex, dichloro-(cyclohepta-l, 4-diene) palladium (II), was characterized spectroscopically. The coordinated diene ring conformations are compared to the minimum energy conformations recently calculated by molecular mechanics methods. It is concluded that cycloocta-1 J-diene and cyclohepta-1, 4-diene change little on complexation, while ...