Reactions of germylenes with diazo compounds. New route for the formation of germanium-carbon double-bonded intermediates

P Riviere, A Castel, J Satgé

Index: Riviere, P.; Castel, A.; Satge, J. Journal of the American Chemical Society, 1980 , vol. 102, # 16 p. 5413 - 5415

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Citation Number: 30

Abstract

Evidence consistent with the transient existence of germy1 derivatives containing@, p) a- bonded germanium has accumulated in the last few years.'-" In this field of research, germylenes are a useful starting material for such double-bonded germanium intermediates. For example, oxidation of germylenes or their reactions with azides, nitroso compounds, oxaziridines, or nitrones led to transient> Ge= Y derivatives (Y= 0, NR). 5-7 We report a ...