Journal of the American Chemical Society

The surface of silica as a medium for the radical and ionic decomposition of diacyl peroxides

JE Leffler, JT Barbas

Index: Journal of the American Chemical Society, , vol. 103, # 26 p. 7768 - 7773

Full Text: HTML

Citation Number: 27

Abstract

... 0002-7863/81/1503-7768$01.25/0 0 1981 American Chemical Society ... The high rate of decomposition of 2 on silica led us to expect a high proportion of ... a site preemption effect3 which will alter the proportions of the peroxide adsorbed on various chemically nonequivalent sites. ...