Gold (I)??Catalyzed Unprecedented Rearrangement Reaction Between 2??Aminobenzaldehydes with Propargyl Amines: An Expedient Route to 3??Aminoquinolines

NT Patil, VS Raut, VS Shinde, G Gayatri…

Index: Patil, Nitin T.; Raut, Vivek S.; Shinde, Valmik S.; Gayatri, Gaddamanugu; Sastry, G. Narahari Chemistry - A European Journal, 2012 , vol. 18, # 18 p. 5530 - 5535

Full Text: HTML

Citation Number: 19

Abstract

A great number of novel transformations have appeared during the last decade based on the gold-catalyzed activation of alkynes.[1] A historical retrospect on the progress in this area reveals that gold–alkyne chemistry is based on three pillars: addition reactions,[1g, v] substitution reactions,[1a] and rearrangement reactions. Of particular interest is the rearrangement reaction, which enables the generation of unusual intermediates and ...