Tetrahedron

Biomimetic methyl transfer to olefins

M Julia, C Marazano

Index: Julia, M.; Marazano, C. Tetrahedron, 1985 ,  vol. 41,  # 18  p. 3717 - 3724

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Citation Number: 19

Abstract

Conditions have been found under which trisubstituted olefins can be methylated with diaryl methyl sulfonium salts in 2, 6-di-t-butylpyridine. The pattern of methylated compound's formed is similar to that of the enzymatic methylation of Δ24 steroids side chains with S- ...