A Joint Experimental and Computational Study on the Electronic Communication in Diethynylaryl??Bridged (η5??C5H5) Fe (η2??dppe) and (η5??C5H5) Fe (CO) 2 Units

…, S Santi, C Durante, A Ricci, C Lo Sterzo

Index: Medei, Laura; Orian, Laura; Semeikin, Oleg V.; Peterleitner, Mikhail G.; Ustynyuk, Nikolai A.; Santi, Saverio; Durante, Christian; Ricci, Antonella; Lo Sterzo, Claudio European Journal of Inorganic Chemistry, 2006 , # 13 p. 2582 - 2597

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Citation Number: 22

Abstract

Abstract A family of bimetallic complexes [Cp (CO) 2 Fe–C≡ C–Ar–C≡ C–Fe (CO) 2 Cp]{Cp= C 5 H 5; 6a–g: Ar= C 4 H 2 S (a), 3-(C 4 H 9)-C 4 HS (b), 3-(C 16 H 33)-C 4 HS (c), C 6 H 4 (d), 2, 5-bis (OC 4 H 9)-C 6 H 2 (e), 2, 5-bis (OC 8 H 17)-C 6 H 2 (f),(C 6 H 4) 2 (g)} was prepared by the three-step Pd-catalysed extended one-pot (EOP) synthetic protocol from Bu 3 Sn–C≡ CH, X–Ar–X (X= I, Br) and Cp (CO) 2 FeI. Complexes 6a, d, g were then ...