Photocatalysis of Perfluorinated Oligo (p-Phenylene) s.

K Maruo, Y Wada, S Yanagida

Index: Maruo, Katsuya; Wada, Yuji; Yanagida, Shozo Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 12 p. 3439 - 3449

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Citation Number: 23

Abstract

Perfluorination of oligo (p-phenylene) s (OPP-n), biphenyl (OPP-2) to p-quaterphenyl (OPP- 4), induces various changes in the spectral and physical characteristics of OPP-n; a hypsochromic shift of their absorption spectra, a decrease in their fluorescence quantum yields, an increase in their fluorescence lifetimes, and a positive shift of their oxidation potentials. The resulting perfluorinated oligo (p-phenylene) s (F-OPP-n, n= 3 and 4) shows ...