Synlett

A new insight into the oxidation of cyclododecane with hydrogen peroxide in the presence of iron-substituted polyoxotungstates

…, MGPMS Neves, JAS Cavaleiro, AMV Cavaleiro

Index: Santos, Isabel C. M. S.; Simoes, Mario M. Q.; Balula, M. Salete S.; Neves, M. Graca P. M. S.; Cavaleiro, Jose A. S.; Cavaleiro, Ana M. V. Synlett, 2008 , # 11 p. 1623 - 1626

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Citation Number: 7

Abstract

Abstract The catalytic homogeneous oxidation of cyclododecane with hydrogen peroxide in the presence of tetrabutylammonium salts of iron-substituted Keggin-type polyoxotungstates of general formula (TBA) 4 H z XW 11 Fe (H 2 O) O 39· nH 2 O (where X= P, Si, B, and z= 0- 2) is described. In the reaction conditions reported, the corresponding alcohol, ketone, and hydroperoxide are obtained as the main reaction products. The catalytic activity of the ...