A NEW SYNTHESIS OF ALKYL FLUORIDES: THE PYROLYSIS OF 2-ALKYLPSEUDOURONIUM FLUORIDES AND FLUOROBORATES

JH Amin, J Newton…

Index: Amin,J.H. et al. Canadian Journal of Chemistry, 1965 , vol. 43, p. 3173 - 3177

Full Text: HTML

Citation Number: 4

Abstract

The pyrolysis of 2-alkylpseudouronium fluorides and fluoroborates at approximately 185° gave alkyl fluorides in yields of up to 77%. The method is most useful for the preparation of primary alkyl fluorides; attempts to prepare secondary fluorides, such as cyclohexyl fluoride, gave the corresponding alkenes.

Ionic liquids as recyclable solvents for diethylaminosulfur ...

[Das, Saibal; Chandrasekhar, Srivari; Yadav, Jhillu Singh; Gree, Rene Tetrahedron Letters, 2007 , vol. 48, # 30 p. 5305 - 5307]

Activation of tetrabutylammonium hydrogen difluoride with py...

[Moughamir, Khadija; Atmani, Aziz; Mestdagh, Helene; Rolando, Christian; Francesch, Charlette Tetrahedron Letters, 1998 , vol. 39, # 40 p. 7305 - 7306]

Halogen-Exchange Fluorination of Primary Alkyl Halides Using...

[Yoneda, Norihiko; Fukuhara, Tsuyoshi; Yamagishi, Ken; Suzuki, Akira Chemistry Letters, 1987 , p. 1675 - 1678]

Homogeneous nucleophilic radiofluorination and fluorination ...

[Mathiessen, Bente; Jensen, Andreas T. I.; Zhuravlev, Fedor Chemistry - A European Journal, 2011 , vol. 17, # 28 p. 7796 - 7805]

Use of polyethylene glycol in the synthesis of alkyl fluorid...

[Badone, Domenico; Jommi, Giancarlo; Pagliarin, Roberto; Tavecchia, Paolo Synthesis, 1987 , # 10 p. 920 - 921]