Synthesis of S-alkyl alkanethioates via 1-iodoalk-1-enyldialkylboranes

M Hoshi, Y Masuda, A Arase

Index: Hoshi, Masayuki; Masuda, Yuzuru; Arase, Akira Journal of the Chemical Society, Chemical Communications, 1985 , # 11 p. 714 - 715

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Abstract

S-Alkyl alkanethioates were formed in high yields by successive reactions of 1 -iodoalk-1-enyl- bis( 1,2-dimethyIpropyl)boranes with at kylthiomagnesium bromides and alkaline hydrogen peroxide. ... There have been few studies on the synthesis of substituted alkenylboranes by the introduction of a substituent onto the a-alkenyl carbon atom of alk-1-enylboranes.1 In the course of studies to modify the alkenyl moiety of alkenylboranes, we found that S-alkyl ...