The Journal of Organic Chemistry

Inductive Effects on the Position of a Ring-Chain Equilibrium1

RH Eastman, K Tamaribuchi

Index: Eastman,R.H.; Tamaribuchi,K. Journal of Organic Chemistry, 1965 , vol. 30, p. 1671 - 1673

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Citation Number: 2

Abstract

2, 5-Bis (trichloromethy1)-N-(l-hydroxy-2, 2, 2-trichloroethyl)-4-iminodioxolane (la), Wallach's compound (C, H4ClgN03), was prepared as previously described4 and recrystallized from benzene: mp 122-123'(lit. 4 mp 122-123'); vmaX 1745 em.-'; nmr (dimethyl sulfoxide) 8 5.47 (doublet, J= 7 cPs), 5.98 (doublet, J= 0.8 cPs), 6.72 (doublet, J= 0.8 cPs), and 7.75 (doublet, J= 7 cPs); this last peak was washed out on addition of DzO.