Tetrahedron Letters

Silicon in organic synthesis. 14. Five ring annulation processes based upon thermal rearrangement of (1-trimethylsilylcyclopropyl) ethylenes

LA Paquette, GJ Wells, KA Horn, TH Yan

Index: Paquette, Leo A.; Wells, Gregory J.; Horn, Keith A.; Yan, Tu-Hsin Tetrahedron Letters, 1982 , vol. 23, # 3 p. 263 - 266

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Citation Number: 24

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Pyrolysis of (1-trimethylsilylcyclopropyl)ethylenes affords silyl substituted cyclopentenes in high yield. Subsequent reaction of these products with varied electrophiles forms the basis of a new and versatile five-ring annulation sequence. ... (c)earlier references cited in these papers.

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