ORGANIC PHOSPHORUS COMPOUNDS 106.1 A 31P-NMR STUDY OF PHOSPHINOUS-, PHOSPHINIC-, AND THIOPHOSPHINIC AMIDES

L Maier, PJ Diel

Index: Maier, Ludwig; Diel, Peter J. Phosphorus, Sulfur and Silicon and Related Elements, 1996 , vol. 115, p. 273 - 300

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Citation Number: 8

Abstract

Abstract The synthesis, physical, chemical and spectroscopic properties of eight different types of phosphinous-, phosphinic-and thiophosphinic amides are reported. It is shown that the 31P-chem. shifts of tertiary amides are at lower magnetic field than that of secondary amides. As an exception, in the bis (tertiary butyl) series this trend is reversed.