Journal of the American Chemical Society

Vinyl cations. 42. Synthesis and solvolysis of substituted 1-cyclobutenyl nonaflates

M Hanack, G Auchter

Index: Hanack,M.; Auchter,G. Journal of the American Chemical Society, 1985 , vol. 107, p. 5238

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Citation Number: 17

Abstract

Abstract: The 2-, 3-and 4-substituted as well as bicyclic nonaflates 19-27 were prepared by treating the corresponding cyclobutanones with nonafluorobutanesulfonic acid anhydride in the presence of 2, 6-di-tert-butyl-4-methylpyridine as the buffer. Some of the substituted cyclobutanones were prepared by slight modification of the reported procedures. The kinetic and product studies of the 1-cyclobutenyl nonaflates were carried out in TFE-water ...