Canadian Journal of Chemistry

Synthetic application of α-hydroxydiazene systems. I. Esters from radical chain reactions of unsaturated compounds with 2-hydroxy-2, 5, 5-trimethyl-Δ3-1, 3, 4- …

P Knittel, J Warkentin

Index: Knittel,P.; Warkentin,J. Canadian Journal of Chemistry, 1976 , vol. 54, p. 1341 - 1344

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Citation Number: 2

Abstract

2-Hydroxy-2, 5, 5-trimethyl-Δ3-1, 3, 4-oxadiazoline (1) reacts with acetylenic and olefinic unsaturated systems by addition of the 2-acetoxy-2-propyl group and a hydrogen atom, respectively, to the two atoms forming the multiple bond. The regiochemistry of addition to